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Give a curved-arrow mechanism for (a) the racemization shown in... | Filo
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SOLVED: The rate constants for racemization (kr) and dissociation (kd) of [FeL3]^4-(H2L=26.12) atseveral temperatures, T, are given in the table.(a) Determine Δ H^† and Δ S^† for each reaction.What can you deduce about the mechanism of racemization? T / K 288 294 298 303 308 kr× 10^5 / s^-1 0.5 1.0 2.7 7.6 13.4 kd× 10^5 / s^-1 0.5 1.0 2.8 7.7 14.0
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